2021
313. "Rationalizing the influence of α-cationic phospholes on pi-catalysis". I. Cortés, J. J. Cabrera-Trujillo, I. Fernández, Dalton Trans. 2021, 50, 18036. pdf
312. "Nature of C-I···π halogen bonding and its role in organocatalysis". S- Portela, I. Fernández, Eur. J. Org. Chem. 2021, 45, 6102. pdf
311. "Stannylenes based on pyrrole-phosphane and dipyrromethanediphosphane scaffolds: Syntheses and behavior as PSnP pincer Ligands". J. A. Cabeza, I. Fernández, P. García-Álvarez, R. García-Soriano, C. J. Laglera-Gándara, R. Torala, Dalton Trans. 2021, 50, 16122. pdf
310. HOT PAPER"Gold-Catalyzed Reaction of Propargyl Esters and Alkynylsilanes: Synthesis of Vinylallene Derivatives through a Twofold 1,2-Rearrangement". O. Bernardo, S. González-Pelayo, I. Fernández, L. A. López, Angew. Chem. Int. Ed. 2021, 22, 25258. pdf
309. HOT PAPER"Reduction of Nitrogen Oxides by Hydrogen with Rh(I)-Pt(II) Olefin Complexes as Catalysts". P. Jurt, A. S. Abels, J. J. Gamboa-Carballo, I. Fernández, G. Le Corre, M. Aebli, M. G. Baker, F. Eiler, F. Müller, M. Wörle, R. Verel, S. Gauthier, M. Trincado, T. L. Gianetti, H. Grützmacher, Angew. Chem. Int .Ed. 2021, 22, 25372. pdf
308. "Regioselective Monoborylation of Spirocyclobutenes". L. Novoa, L. Trulli, I. Fernández, A. Parra, M. Tortosa, Org. Lett. 2021, 23, 7434. pdf
307. "A Dicoordinate Gold(I)–Ethylene Complex". M. Navarro, J. Miranda-Pizarro, J. J. Moreno, C. Navarro-Gilabert, I. Fernández, J. Campos, Chem. Commun. 2021, 57, 9280. pdf HIGHLIGHTED in Chemistry Views, see here
306. "Iron(II) and Copper(I) Control the Total Regioselectivity in the Hydrobromination of Alkenes". D. A. Cruz, V. Sinka, P. de Armas, H. S. Steingruber, I. Fernández, V. S. Martín, P. O. Miranda, J. I. Padrón, Org. Lett. 2021, 23, 6105. pdf
305. "Helically Arranged Chiral Molecular Nanographenes". P. Izquierdo-García, J. M. Fernández-García, I. Fernández, J. Perles, N. Martín, J. Am. Chem. Soc. 2021, 143, 11864. pdf
304. "Scope and mechanistic investigations of Pd-catalyzed coupling/cyclizations and cycloisomerizations of allenyl malonates". L. E. Vine, R. D. Reeves, E. M. Landwehr, I. Fernández, J. M. Schomaker, ACS Catal. 2021, 11, 9485. pdf
303. HOT PAPER"Factors Controlling the Aluminium(I)-meta-selective C-H Activation in Arenes". J. J. Cabrera-Trujillo, I. Fernández, Chem. Eur. J. 2021, 27, 12422. pdf
302. BOOK CHAPTER "Quantifying Aromaticity According to the Energetic criterion". M. Alonso, I. Fernández, in Aromaticity: Modern Computational Methods and Applications, ch. 6, Ed. I. Fernández, Elsevier, 2021. pdf
301. “Reactivity of Stabilized Vinyldiazo Compounds toward Alkenyl- and Alkynylsilanes under Gold-Catalysis: Regio- and Stereoselective Synthesis of Skipped Dienes and Enynes”. O. Bernardo, K. Yamamoto, I. Fernández, L. A. López, Org. Lett. 2021, 1, 623. pdf
300. “Metal–CO Bonding in Mononuclear Transition Metal Carbonyl Complexes”. G. Frenking, I. Fernández, N. Holzmann, S. Pan, I. Krossing, M. Zhou, JACS Au 2021, 1, 623. pdf
299. “Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn—Zn Bond Cleavage and Cooperative Reactivity”. N. Hidalgo, C. Romero-Pérez, C. Maya, I. Fernández, J. Campos, Organometallics 2021, 40, 1113. pdf
298. “Origin of the Ir-Si Bond Shortening in Ir-NSiN complexes”. P. García-Orduña, I. Fernández, L. A. Oro, F. J. Fernández-Alvarez, Dalton Trans. 2021, 50, 5951. pdf
297. HOT PAPER “Lewis Acid‐Catalyzed Diels‐Alder Reactions: Reactivity Trends across the Periodic Table ”. P. Vermeeren, M. Dalla Tiezza, M. van Dongen, I. Fernández, F. M. Bickelhaupt, T. A. Hamlin, Chem. Eur. J. 2021, 27, 10610. pdf
296. “Catalysis by Bidentate Iodine(III)-based Halogen donors: Surpassing the activity of strong Lewis acids”. S. Portela, J. J. Cabrera-Trujillo, I. Fernández, J. Org. Chem. 2021, 27, 5180. pdf
295. “Nature of the Hydrogen Bond Enhanced Halogen Bond”. S. Portela I. Fernández, Molecules 2021, 26, 1885. pdf (INVITED FOR Special Issue Chemical Bonding: A Commemorative Special Issue Honoring Professor Linus Pauling)
294. “The Pauli Repulsion-Lowering Concept in Catalysis”. T. A. Hamlin, F. M. Bickelhaupt, I. Fernández, Acc. Chem. Res. 2021, 54, 1972. pdf COVER
293. “Assembly of a Dihydrideborate and two Aryl Nitriles to Form a C,N,N’-Pincer Ligand Coordinated to Osmium”. J. C. Babón, M. A. Esteruelas, I. Fernández, A. M. López, E. Oñate, Organometallics 2021, 40, 635. pdf
292. “Reactions of Late First-Row Transition Metal (Fe–Zn) Dichlorides with a PGeP Pincer Germylene”. A. Arauzo, J. A. Cabeza, I. Fernández, P. García-Álvarez, I. García-Rubio, C. J. Laglera-Gándara, Chem. Eur. J. 2021, 27, 4985. pdf
291. “Iron-promoted dealkylative carbene aminocyclization of δ-arylamino-α-diazoesters”. D. Solé, A. Amenta, C. Campos, I. Fernández, Dalton Trans. 2021, 50, 2167. pdf
290. “Highly Enantioselective Cobalt-Catalyzed (3 + 2) Cycloadditions of Alkynylidenecyclopropanes”. E. Da Concepción, I. Fernández, J. L. Mascareñas, F. López, Angew. Chem. Int. Ed. 2021, 60, 8182. pdf
289. “Understanding the C–F Bond Activation Mediated by Frustrated Lewis Pairs: Crucial Role of Noncovalent Interactions". J. J. Cabrera-Trujillo, I. Fernández, Chem. Eur. J. 2021, 27, 3823. pdf
288. HOT PAPER “Bifunctional Hydrogen Bond Donor-Catalyzed Diels-Alder Reactions: Origin of Stereoselectivity and Rate Enhancement ”. P. Vermeeren, T. A. Hamlin, F. M. Bickelhaupt, I. Fernández, Chem. Eur. J. 2021, 27, 5180. pdf COVER
287. “Catalytic Conversion of Alkynes to a-Vinyl Sulfides Mediated by Carbene-linker-Carbene (CXC) Rhodium and Iridium Complexes”. L. C. Tolley, I. Fernández, D. I. Bezuidenhout, G. Guisado-Barrios, Catal. Sci. Technol. 2021, 11, 516. pdf