Proyectos de Investigación

2024-pub

384. "π-Extended 4,5-Fused Bis-Fluorene: Highly Open-Shell Compounds and their Cationic Tetrathiafulvalene Derivatives"F. Lirette, V. B. R. Pedersen, F. Gagnon, M. B. Nielsen, I. Fernández, J.-F. Morin, Angew. Chem. Int. Ed. 2024, in presspdf 

383. "Chiral Stacks of a Curved Nanographene"Z. Zhang, D. Csókás, I. Fernández, M. Stuparu, Chem 2024, 10, 3199. pdf 

382. "Lewis-Acid-Promoted Visible-Light-Mediated C(sp3)–H Bond Functionalization of Arylvinylpyridines via Diradical Hydrogen Atom Transfer"Y. Hu, Q. Liu, X. Zhou, Y. Huang, I. Fernández, Y. Xiong, Org. Lett. 2024, in presspdf 

381. "A Lead-µ2-Tetrylide Complex with Osmium(IV) Terminal Components"J. A. Cabeza, M. A. Esteruelas, I. Fernández, S. Izquierdo, E. Oñate, Inorg. Chem. 2024, 63, 15563. pdf 

380. "Exploring enantiopure zinc-scorpionates as catalysts for the preparation of polylactides, cyclic carbonates, and polycarbonates"M. Navarro, S. Sobrino, I. Fernández, A. Lara-Sánchez A. Garcés, L. F. Sánchez-Barba, Dalton Trans. 2024, 53, 13933. pdf 

379. "Carbene Decorated Geometrically Constrained Borylenes for Bond Activations"B. Chakraborty, D. González-Pinardo, I. Fernández, A. Phukan, Inorg. Chem. 2024, 63, 14969pdf 

378. "From Cyclopropene to Housane Derivatives Via Intramolecular Cyclopropanation"D. Coto, D. Suárez-García, S. Mata, I. Fernández, L. A. López, R. Vicente, Angew. Chem. Int. Ed. 2024, in presspdf 

377. "Catalytic Activity of Mono-and Bimetallic Rhodium(I) and Iridium(I) Complexes Bearing Carbon-Ether-Carbon (COC) Ligand for the Intramolecular Cyclization of 4-Pentynoic Acid"H. Boddaert, L. C. Tolley, C. Mejuto, A. González, M. Martín, E. Sola, I. Fernández, A. J. Karhu, D. I. Bezuidenhout, G. Guisado-Barrios, Eur. J. Org. Chem. 2024, in presspdf 

376. "Cobalt-Catalyzed (3+2) Cycloaddition of Cyclopropene-tethered Alkynes: Versatile Access to Bicyclic Cyclopentadienyl Systems and their CpM Complexes"C. Lázaro-Milla, E. da Concepción, I. Fernández,* J. L. Mascareñas, F. López, ACS Catal. 202414, 11574. pdf 

375. "Origin of the Felkin-Anh(-Eisenstein) Model: a Quantitative Rationalization of a Seminal Concept"D. González-Pinardo, F. M. Bickelhaupt, I. Fernández, Chem. Sci. 2024, 15, 12380. pdf 

374. "Understanding the Role of Internal Lewis Acids in the Catalytic Activity of Urea-Based Hydrogen Donors"S. Portela, I. Fernández, Eur. J. Org. Chem. 2024, 27, e202400507. pdf SPECIAL ISSUE "Physical Organic Chemistry"

373. "Activation of σ-bonds by Group 13/Ylide-based Ambiphiles: Understanding and Design"D. González-Pinardo, F. Krämer, F. Breher, I. Fernández, ChemistryEurope 2024, 2, e202400020. pdf selected for COVER PAGE

372. "Understanding the Regiodivergence Between Hydroarylation and Trifluoromethylarylation of 1,3-Dienes using anilines in HFIP"C. Corral Suarez, I. Fernández, I. Colomer, JACS Au 2024, 4, 1744. pdf 

371. "A Mixed-Valence Ti(II)/Ti(III) Inverted Sandwich Compound as a Regioselective Catalyst for the uncommon 1,3,5-Alkyne Cyclotrimerization"E. Álvarez-Ruiz, I. Sancho, M. Navarro, I. Fernández, C. Santamaría, A. Hernán-Gómez, Inorg. Chem. 2024, 63, 8642. pdf 

370. "Enantioselective synthesis of α-aryl α-hydrazino phosphonates"S. Alberca, J. Romero-Parra, I. Fernández, R. Fernández, J. M. Lassaletta, D. Monge, Chem. Sci. 2024, 15, 7725. pdf 

369. "Predisposition in Dynamic Covalent Chemistry: The Role of Non-Covalent Interactions in the Assembly of Tetrahedral Boronate Cages"  M. Rondelli, J. Pasán, I. Fernández, T. Martín, Chem. Eur. J. 2024, 30, e202400896. pdf 

368. "Visible-Light Activation of Diorganyl Bis(pyridylimino) Isoindolide Aluminum(III) Complexes and Their Organometallic Radical Reactivity"O. Wenzel, J. Werner, A. Allgaier, J. van Slageren, I. Fernández, A.-N. Unterreiner, F. Breher, Angew. Chem. Int. Ed. 2024, 63e202402885pdf selected for COVER PAGE

367. "An Unexpected Lewis Acid-Catalyzed Cascade During the Synthesis of the DEF-Benzoxocin Ring System of Nogalamycin and Menogaril: Mechanistic Elucidation by Intermediate Trapping Experiments and Density Functional Theory Studies"H. Liu, A. G. Laporte, D. Gónzalez-Pinardo, I. Fernández, D. Hazelard, P. Compain, J. Org. Chem. 2024, 89, 5634. pdf 

366. "Addition of Allyl Grignard to Nitriles Under Air and Room Temperature. Experimental and Computational Mechanistic Insights in pH-Switchable Synthesis"B. Parra-Cadenas, I. Fernández, F. Carrillo-Hermosilla, J. García-Álvarez, D. Elorriaga, Chem. Sci. 2024, 15, 5929. pdf selected for COVER PAGE

365. "Exploring C-C Bond Formation Reactions for Expanding Azulene Derivatives Linked at the 2- and/or 6-positions"F. P. Mathey, I. Fernández, J.-F. Morin, New J. Chem. 2024, 48, 4801. pdf 

364. "What defines electrophilicity in carbonyl compounds"F. M. Bickelhaupt, I. Fernández, Chem. Sci. 2024, 15, 3980pdf 

363. "A Deeper Insight into the Supramolecular Activation of Oxidative Addition Reactions Involving Pincer-Rhodium(I) Complexes".  T. V. Alves, E. Peris, I. Fernández, ChemPhysChem 2024, 25, e202400022pdf 

362. "Metal Influence on Cyaphide-Azide 1,3-Dipolar Cycloaddition Reactions: Aromaticity and Activation Strain"D. González-Pinardo, J. M. Goicoechea, I. Fernández, Chem. Eur. J. 2024, 30, e202303977pdf 

361. "Intramolecular Dearomative 1,4-Addition of Silyl and Germyl Radicals to a Phenyl Moieties"F. Krämer, J. O. Wenzel, I. Fernández, F. Breher, Dalton Trans. 2024, 53, 2917. pdf 

360. "Rhodium Complexes with a Pyridine-2-yloxy-silyl Based N,Si-ligand: Bonding Situation and Activity as Alkene Hydrogenation Catalysts" A. Gómez-España, P. García-Orduña, F. J. Lahoz, I. Fernández, F. J. Fernández-Álvarez, Organometallics 2024, 43, 402. pdf 

359. "Isonitriles as Alkyl Radical Precursors in Visible Light Mediated Hydro– and Deuterodeamination Reactions" I. Quirós, M. Martín, M. Gomez-Mendoza, M. J. Cabrera-Afonso, M. Liras, I. Fernández, L. Nóvoa, M. Tortosa, Angew. Chem. Int. Ed. 2024, 63, e2023176. pdf 

358. "Mono(Lewis Base)-Stabilized Gallium Iodide: An Unexplored Class of Promising Ligands" S. Ahmed, H. Das, D. González-Pinardo, I. Fernández, A. K. Phukan, Chem. Eur. J. 2024, 30, e202303746pdf 

357. "Quo Vadis CO2 activation: Catalytic Reduction of CO2 to Methanol Using Aluminum and Gallium/Carbon-based Ambiphiles" F. Krämer, J. Paradies, I. Fernández, F. Breher, Chem. Eur. J. 2024, 30e202303380pdf 

356. "Cobalt-catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes" E. da Concepción, I. Fernández, J. L. Mascareñas, F. López, Adv. Synth. Catal. 2024, 366, 762pdf 

355. "SurfinPES: Performing automated analysis of activation strain, energy decomposition, and reaction force" A. Quintal, E. Dzib, F. Murillo, F. Ortíz-Chi, I. Fernández, G. Merino, Int. J. Quantum Chem. 2024, 124e27194pdf 

354. "A crystalline aluminum/carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media" F. Krämer, J. Paradies, I. Fernández, F. Breher, Nat. Chem. 2024, 16, 63. pdf