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Recientes

 

Indium-Mediated Preparation of Bis(α-hydroxyallenes) or α,α′-Dihydroxyallenynes and Further Gold-Catalyzed Cyclizations. T. Martínez del Campo, D. San Martín, L. Gamarra, E. Cerrón, S. Cembellín, H. Yanai, P. Almendros. J. Org. Chem. 2024, 89, 14228-14232. DOI: 10.1021/acs.joc.4c01648

Figure 1

Gold-Catalyzed Orthogonal and Chemocontrolled Synthesis of [4-7-6] Tricycles from 1,5-Diynes. P. Almendros, S. H. Hoshikawa, J. M. Alonso, T. Matsumoto, H. Yanai. Adv. Synth. Catal. 2024, 366, 3683-3688. https://doi.org/10.1002/adsc.202400605. 

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Unveiling the Use of 1,1-Bis(triflyl)ethylene as CF3SO2CH═CH2 Source with the Assistance of (n-Bu)4NF: Synthesis of 3-[(Trifluoromethyl)sulfonyl]cyclobut-1-enes. A. S. Petcu, C. Lázaro-Milla, J. M. Alonso, P. Almendros. Org. Lett. 2024, 21, 4560-4565 

 

 

Regioselectivity Control in the Synthesis of Linear Conjugated Dienes Enabled by Manganese(I)-Catalyzed C–H Activation. D. G. Matesanz, L. Gamarra, T. Martínez del Campo, P. Almendros, S. Cembellín. ACS Catal. 2023, 13, 14523−14529


Straightforward Synthesis of Bis[(trifluoromethyl)sulfonyl]ethylated Isocoumarins from 2-Ethynylbenzoates. A. Sonia Petcu, C. Lázaro-Milla, F. J. Rodríguez, I. Iriepa, Ó. M. Bautista-Aguilera, C. Aragoncillo, J. M. Alonso, P. Almendros. J. Org. Chem. 2023, 88, 7373−7380


Highlighting the Rich Chemistry of the Allenone Moiety. J. M. Alonso, P. Almendros. Adv. Synth. Catal. 2023365, 1–54


Indium-Promoted Butenolide Synthesis through Consecutive C−C and C−O Bonds Formation in Aqueous Tetrahydrofuran Enabled by Radicals. H. Yanai, M. R. Márquez, S. Cembellín, T. Martínez del Campo, P. Almendros. Org. Chem. Front. 2023, 10, 1773–1779


2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols. I. Martín-Mejías, A. S. Petcu, J. M. Alonso, C. Aragoncillo, P. Almendros. Adv. Synth. Catal. 2022, 364, 3954–3959


Au(I) as a π-Lewis Base Catalyst: Controlled Synthesis of Sterically Congested Bis(triflyl)enals from α-Allenols. M. Toledano-Pinedo, T. Martínez del Campo, H. Yanai, P. Almendros. ACS Catal. 2022, 12, 11675–11681


Regioselectivity Switch Based on the Stoichiometry: Stereoselective Synthesis of Trisubstituted Vinyl Epoxides by Cu-Catalyzed 3-exo-trig Cyclization of α-Allenols. P. Esteban, F. Herrera, D. San Martín, A. Luna, P. Almendros. Adv. Synth. Catal. 2022, 364, 3289–3294

 


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