Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement

Cabeza, J. A.; García-Álvarez, P.; Gómez-Gallego, M.; González-Álvarez, L.; D. Merinero, A.; Sierra, M. A. Chem. Eur. J. 2019, 25, 2222 – 2225

 

Reversible Carbene Insertion into a Ge–N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes

Álvarez-Rodríguez, L.  Cabeza, J. A.; García-Álvarez, P.; Gómez-Gallego, M.; González-Álvarez, L.; D. Merinero, A.; Sierra, M. A. Chem. Eur. J. 2019, 25, 1588 – 1594.

 

Understanding the Reactivity of Group 6 Alkynyl Metal (M = Cr, W) Fischer Carbene Complexes with Multireactive Masked Dienes

Collado, A.; Gómez-Gallego, M.; Santiago, A.; Sierra, M. A. Eur. J. Org. Chem. 2019, 369–377.

 

Central (S) to Central (M = Ir, Rh) to Planar (Metallocene, M = Fe, Ru) Chirality Transfer Using Sulfoxide Substituted Mesoionic Carbene Ligands: Synthesis of Bimetallic Planar-Chiral Metallocenes

Avello, M. G.; de la Torre, Sierra, M. A.; Gornitzka, H.; Hemmert, C. .Chem. Eur. J. 2019, 25, 13344-13353. 

 

Bio-Organometallic Derivatives of Antibacterial Drugs

Sierra, M. A.; Casarrubios, L.; de la Torre, M. C.  Chem. Eur. J. 2019, 25, 7232–7242.

 

Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior.

Merinero, A. D.; Collado, A.; Casarrubios. L.; Gómez-Gallego, M.; Ramírez de Arellano C.; Caballero, A.; Zapata, F. ; Sierra; M. A.  Inorg. Chem. 2019, 58, 16267-16278.

 

Cabeza,J. A.;  García-Álvarez,P.; Gómez-Gallego, M.;  González-Álvarez,L.; Merinero, A. D.;  Sierra, M. A. Chem. Eur. J. 2019, 25, 8635-8642.